

Having seen this webpage https://www.draytoncontrols.co.uk/news/opentherm-explained , which kind of modulation do you have? Long boiler runs are not always bad.
Also, are you able to use the living room TRVs to restrict the livingroom radiators heat output while keeping what you have set as the main setpoint, in the use case you detailed. That would avoid having the main thermostat triggered off too soon.

From the site: with opentherm modulation “the boiler will run for longer periods but it will be producing water at lower temperatures, resulting in less energy being used and maximising the time spent in the higher efficiency condensing mode.” So, longer running times should not be a problem in your setup.